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Effect of increasing [d-xylonate] or [d-xylose] on (kcat/KHPi)obs for dianion activation of the catalyzed reactions of truncated substrates (Scheme 3). (A) Ec6PGDH-catalyzed reactions of d-xylonate (●) and LmG6PDH-catalyzed oxidation of d-xylose by NADP (■). (B) ScPGI-catalyzed isomerization of d-xylose (●).
