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. Author manuscript; available in PMC: 2021 Dec 14.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Oct 15;59(51):23169–23173. doi: 10.1002/anie.202011363

Scheme 3.

Scheme 3.

Total synthesis of the labdane diterpenoid andrographolide.a

aYields are of material isolated by silica gel chromatography. See Supporting Information for further experimental details.