Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Stepwise generation of superoxide, peroxide, and hydroperoxide heme analogues and relevant thermodynamic square scheme (E° as determined vs Fc+/0 and pKa) and OO─H BDFE of ferric heme hydroperoxide. ArF = 2,6-difluorophenyl group. Upper right: the previously studied ferric heme peroxide [(F8)FeIII─(η2:O22−)]−.[3]
