Table 3.
DAK and sterol composition of no chemically interesterified (NCIE) and chemically interesterified (CIE) palm oil, NCIE and CIE rapeseed oil, CIE shea butter, CIE mix of raw and hydrogenated rapeseed oil (70/30 and 60/40), CIE mix of rapeseed and palm oil.
| Compounds | NCIE Palm Oil | CIE Palm Oil | NCIE Rapeseed Oil (Raw) | CIE Rapeseed Oil (Raw) | CIE 1 | CIE 2 | CIE 3 | CIE 4 |
|---|---|---|---|---|---|---|---|---|
| DAK (mg/g) | ||||||||
| C15:0-C15:0 | - | 1.5 ± 0.04 | - | 49.0 ± 1.32 | 3.0 | 28.0 | 40.7 | 27.3 |
| C16:0-C16:0 | - | 3.6 ± 0.11 | - | 2.3 ± 0.07 | 7.5 | 4.1 | 0.9 | 1.8 |
| C16:0-C18:1 | - | 9.5 ± 0.24 | - | 1.5 ± 0.04 | 9.6 | 8.1 | 7.0 | 4.1 |
| C16:0-C18:0 | - | 0.7 ± 0.03 | - | 0.2 ± 0.01 | 76.0 | 3.3 | 5.4 | 0.1 |
| C18:1-C18:1 | - | 5.0 ± 0.12 | - | 13.0 ± 0.31 | 7.5 | 57.7 | 31.4 | 5.5 |
| C18:1-C18:0 | - | 0.9 ± 0.02 | - | 0.8 ± 0.02 | 10.3 | 45.0 | 49.8 | 0.4 |
| C18:0-C18:0 | - | 0.2 ± 0.01 | - | 0.0 ± 0.00 | 3.7 | 9.4 | 19.5 | 0.2 |
| C18:1-C20:0 | - | <LOQ | - | <LOQ | 0.4 | <LOQ | 2.1 | <LOQ |
| C18:0-C20:0 | - | <LOQ | - | <LOQ | 0.8 | <LOQ | 1.1 | <LOQ |
| STEROL (mg/kg) | ||||||||
| Cholesterol | 5.9 ± 2.2 | 8.0 ± 2.0 | 13.4 ± 0.5 | 13.1 ± 1.1 | <LOQ | 10.3 | 6.7 | 8.5 |
| Brassicasterol | 7.5 ± 0.9 | 8.4 ± 1.1 | 526.5 ± 4.7 | 539.2 ± 56.0 | <LOQ | 355.4 | 285.9 | 243.9 |
| Campesterol | 113.3 ± 8.5 | 121.2 ± 7.3 | 1994.0 ± 31.2 | 1926.8 ± 178.9 | <LOQ | 1466.2 | 1199.2 | 935.4 |
| Stigmasterol | 47.5 ± 3.5 | 50.2 ± 4.2 | 117.1 ± 1.4 | 122.9 ± 2.9 | 71.0 | 87.1 | 109.0 | 25.0 |
| Clerosterol | <LOQ | <LOQ | 49.1 ± 1.7 | 51.2 ± 2.2 | <LOQ | 14.4 | 10.9 | <LOQ |
| β-Sitosterol | 271.4 ± 30.7 | 282.7 ± 20.2 | 2542.6 ± 24.8 | 2615.9 ± 236.1 | 348.2 | 1778.0 | 1446.8 | 1472.2 |
| Δ-5-Avenasterol | 7.4 ± 4.3 | 10.8 ± 0.6 | 155.5 ± 1.6 | 160.7 ± 11.6 | 868.8 | 152.3 | 132.7 | 129.1 |
| Δ-5-24-Stigmastadienol | <LOQ | <LOQ | 63.9 ± 0.0 | 64.9 ± 1.9 | <LOQ | 21.5 | 16.0 | <LOQ |
NCIE: not chemically interesterified; CIE: chemically interesterified; CIE 1: Shea 100%; CIE 2: mix Rapeseed (Raw/Hydrog 70/30); CIE 3: mix Rapeseed (Raw/Hydrog 60/40); CIE 4: mix Rapeseed/Palm 50/50; -: not detected.