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. 2021 Feb 19;26(4):1089. doi: 10.3390/molecules26041089

Table 2.

Cycloaddition a of CO2 to styrene epoxide in different ionic liquids.

Entry Ionic Liquid Styrene Carbonate Yield/% b
1 [emim][N(CN)2] 0.3
2 [bmim][N(CN)2] 4.9
3 [emim][Cl] 0.5
4 [bmim][Cl] 1.6
5 [emim][NTf2] 0.1
6 [bmim][NTf2] 0.3

a Reaction conditions: styrene epoxide (5 mmol), [Bu4N]Br (0.3% mol vs. epoxide), IL (2.5 mL), CO2 (8 bar), 24 h, 80 °C. b Yield determined by 1H NMR (internal standard method).