Table 2.
Volatile compounds detected in the analyzed samples of genetic lineage C1 of the A. pinguis.
| No. | Compounds | RI a | Code b | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| C1-1 | C1-2 | C1-3 | C1-4 | C1-5 | C1-6 | C1-7 | C1-8 | C1-9 | C1-10 | |||
| 1 | 1-Penten-3-ol | 673 | 0.27 | 0.32 | 0.49 | 0.39 | 0.11 | 0.09 | 0.13 | 0.11 | 0.19 | 0.21 |
| 2 | Pentanal | 677 | - | - | - | - | - | - | - | - | - | - |
| 3 | (Z)-2-Penten-1-ol | 766 | 0.09 | 0.11 | 0.21 | 0.22 | 0.09 | 0.11 | 0.10 | 0.06 | 0.08 | 0.12 |
| 4 | Hexanal | 773 | 2.21 | 0.69 | 0.81 | 1.09 | 1.97 | 2.49 | 1.32 | 0.84 | 0.91 | 0.89 |
| 5 | (Z)-3-Hexen-1-ol | 858 | 1.82 | 2.41 | 1.62 | 1.82 | 0.89 | 2.71 | 1.73 | 1.43 | 1.07 | 0.98 |
| 6 | 1-Hexanol | 867 | 3.39 | 5.43 | 2.22 | 1.73 | 1.52 | 1.90 | 1.48 | 2.29 | 2.07 | 1.87 |
| 7 | α-Pinene | 936 | - | - | - | - | - | - | - | - | - | - |
| 8 | Camphene | 953 | - | - | - | - | - | - | - | - | - | - |
| 9 | Benzaldehyde | 970 | - | - | - | - | - | - | - | - | - | - |
| 10 | β-Pinene | 978 | 0.39 | 0.10 | 0.19 | 0.21 | 0.51 | 0.11 | 0.39 | 0.12 | 0.44 | 0.23 |
| 11 | δ-Elemene | 1324 | - | - | - | - | - | - | - | - | - | - |
| 12 | α-Longipinene | 1350 | 0.22 | 0.02 | 0.03 | 0.06 | 0.12 | 0.03 | 0.02 | 0.08 | 0.06 | 0.05 |
| 13 | α-Ylangene | 1373 | 0.29 | 0.12 | 0.22 | 0.23 | 0.11 | 0.12 | 0.06 | 0.29 | 0.13 | 0.23 |
| 14 | α-Copaene | 1376 | - | - | - | - | - | - | - | - | - | - |
| 15 | Sativene | 1396 | 0.13 | 0.20 | 0.41 | 0.32 | 0.29 | 0.23 | 0.03 | 0.07 | 0.11 | 0.06 |
| 16 | β-Caryophyllene | 1415 | 0.69 | 0.28 | 0.63 | 0.43 | 0.12 | 0.32 | 0.18 | 0.65 | 0.43 | 0.52 |
| 17 | Longifolene | 1417 | 0.89 | 0.41 | 1.08 | 1.06 | 0.98 | 0.57 | 0.49 | 0.83 | 0.71 | 1.20 |
| 18 | β-Ylangene | 1423 | 0.81 | 0.73 | 0.51 | 0.70 | 0.54 | 0.59 | 0.38 | 0.62 | 0.61 | 0.30 |
| 19 | Cedrene | 1427 | 2.72 | 2.22 | 2.71 | 3.91 | 1.20 | 0.89 | 0.80 | 2.39 | 2.33 | 2.41 |
| 20 | 204[M]+, 161 (100), 105(85) | 1431 | - | - | - | - | - | - | - | - | - | - |
| 21 | Thujopsene | 1435 | 0.38 | 0.70 | 1.31 | 2.18 | 2.39 | 0.06 | 0.10 | 0.18 | 0.10 | 0.09 |
| 22 | α-Guaiene | 1439 | - | - | - | - | - | - | - | - | - | - |
| 23 | 204[M]+, 93(100), 81(82) | 1441 | - | - | - | - | - | - | - | - | - | - |
| 24 | 204[M]+, 93(100), 79(85) | 1443 | - | - | - | - | - | - | - | - | - | - |
| 25 | 204[M]+, 119(100), 93(75) | 1445 | 0.38 | 0.13 | 0.29 | 0.52 | 0.21 | 0.05 | 0.06 | 0.11 | 0.08 | 0.72 |
| 26 | α-Himachalene | 1447 | 0.10 | 0.05 | 0.08 | 0.11 | 0.04 | 0.21 | 0.12 | 0.22 | 0.09 | 0.10 |
| 27 | 204[M]+, 91(100), 105(93) | 1453 | 0.22 | 0.10 | 0.08 | 0.23 | 0.07 | 0.21 | 0.10 | 0.18 | 0.08 | 0.22 |
| 28 | Alloaromadendrene | 1457 | 0.40 | 0.04 | 0.17 | 0.09 | 0.32 | 0.13 | 0.23 | 0.07 | 0.05 | 0.48 |
| 29 | γ-Gurjunene | 1470 | 0.12 | 0.06 | 0.04 | 0.39 | 0.05 | 0.21 | 0.09 | 0.07 | 0.08 | 0.41 |
| 30 | β-Himachalene | 1500 | 0.20 | 0.04 | 0.06 | 0.11 | - | - | - | - | - | - |
| 31 | 204[M]+, 119(100), 91(70) | 1503 | 0.19 | 0.06 | 0.07 | 0.09 | 0.21 | 0.09 | 0.06 | 0.21 | 0.06 | 0.11 |
| 32 | Cuparene | 1505 | - | - | - | - | - | - | - | - | - | - |
| 33 | δ-Cadinene | 1517 | - | - | - | - | - | - | - | - | - | - |
| 34 | β-Sesquiphellandrene | 1520 | 0.03 | 0.06 | 0.07 | 0.32 | 0.06 | 0.07 | 0.11 | 0.12 | 0.06 | 0.12 |
| 35 | 204[M]+, 119(100), 91(66) | 1524 | - | - | - | - | - | - | - | - | - | - |
| 36 | 204[M]+, 69(100), 91(38) | 1530 | - | - | - | - | - | - | - | - | - | - |
| 37 | 216[M]+, 109(100), 145(75) | 1533 | 0.99 | 0.69 | 1.19 | 1.09 | 1.08 | 4.59 | 4.78 | 2.89 | 2.67 | 3.11 |
| 38 | α-Copaene-11-ol | 1540 | - | - | - | - | - | - | - | - | - | - |
| 39 | Longicamphenylone | 1559 | - | - | - | - | - | - | - | - | - | - |
| 40 | Deoxopinguisone | 1563 | 15.69 | 11.82 | 14.39 | 13.49 | 20.21 | 11.69 | 12.42 | 20.41 | 17.22 | 16.70 |
| 41 | 220[M]+, 91(100), 110(90) | 1585 | - | - | - | - | - | - | - | - | - | - |
| 42 | 204[M]+, 137(100), 81(60) | 1593 | - | - | - | - | - | - | - | - | - | - |
| 43 | 218[M]+, 91(100), 119(57) | 1603 | 0.81 | 0.62 | 0.11 | 0.40 | 0.13 | 0.22 | 0.08 | 0.59 | 0.57 | 0.87 |
| 44 | 220[M]+, 135(100), 91(60) | 1620 | - | - | - | - | - | - | - | - | - | - |
| 45 | 220[M]+, 110(100), 91(97) | 1626 | - | - | - | - | - | - | - | - | - | - |
| 46 | 220[M]+, 91(100), 79(82) | 1633 | 0.29 | 2.37 | 0.69 | 1.18 | 0.51 | 1.38 | 1.59 | 0.61 | 0.82 | 1.33 |
| 47 | Longiverbenone | 1641 | - | - | - | - | - | - | - | - | - | - |
| 48 | δ-Cadinol | 1646 | - | - | - | - | - | - | - | - | - | - |
| 49 | Aromadendreneoxide-(2) | 1678 | - | - | - | - | - | - | - | - | - | - |
| 50 | 222[M]+, 95(100), 81(75) | 1685 | 0.09 | 0.22 | 0.19 | 0.51 | 0.63 | 0.21 | 0.11 | 0.41 | 0.09 | 0.63 |
| 51 | 220[M]+, 81(100), 67(90) | 1687 | 0.61 | 0.70 | 0.78 | 0.63 | 0.13 | 0.32 | 0.69 | 0.61 | 1.02 | 0.23 |
| 52 | Pinguisone | 1705 | 56.39 | 58.12 | 55.91 | 55.33 | 50.28 | 50.67 | 51.70 | 47.08 | 47.42 | 51.08 |
| 53 | Isopinguisone | 1712 | - | - | - | - | - | - | - | - | - | - |
| 54 | Bryopterin A | 1735 | - | - | - | - | - | - | - | - | - | - |
| 55 | Dihydrobryopterin A | 1755 | 0.12 | 2.99 | 3.18 | 1.52 | 0.12 | 0.21 | 0.32 | 0.42 | 0.51 | 0.05 |
| 56 | Methyl norpinguisonate | 1791 | - | - | - | - | - | - | - | - | - | - |
| 57 | 236[M]+, 95(100), 109(85) | 1846 | - | - | - | - | - | - | - | - | - | - |
| 58 | 244[M]+, 189(100), 105(15) | 1851 | - | - | - | - | - | - | - | - | - | - |
| 59 | 246[M]+, 192(100), 91(43) | 1882 | - | - | - | - | - | 0.08 | 0.09 | 0.11 | 0.12 | 0.13 |
| 60 | Costunolide | 1914 | 6.81 | 6.29 | 8.72 | 8.38 | 12.61 | 17.99 | 18.21 | 14.81 | 18.09 | 12.31 |
| 61 | 247[M]+, 147(100), 119(75) | 1934 | - | - | - | - | - | - | - | - | - | - |
| 62 | 276[M]+, 108(100), 79(26) | 1938 | - | - | - | - | - | - | - | - | - | - |
| 63 | 276[M]+, 108(100), 79(35) | 1951 | - | - | - | - | - | - | - | - | - | - |
| 64 | 272[M]+, 81(100), 161(75) | 1955 | - | - | - | - | - | - | - | - | - | - |
| 65 | 217[M]+, 108(100), 79(50) | 1989 | - | - | - | - | - | - | - | - | - | - |
| 66 | 230[M]+, 108(100), 79(35) | 2051 | - | - | - | - | - | - | - | - | - | - |
| Total | 97.74 | 98.10 | 98.46 | 98.74 | 97.50 | 98.55 | 97.97 | 98.88 | 98.27 | 97.76 | ||
| % Identified | 94.16 | 93.21 | 95.06 | 94.09 | 94.53 | 91.40 | 90.41 | 93.16 | 92.76 | 90.41 | ||
| Including: | ||||||||||||
| Aliphatics | 7.78 | 8.96 | 5.35 | 5.25 | 4.58 | 7.30 | 4.76 | 4.73 | 4.32 | 4.07 | ||
| Aromatics | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | ||
| Monoterpene hydrocarbons | 0.39 | 0.10 | 0.19 | 0.21 | 0.51 | 0.11 | 0.39 | 0.12 | 0.44 | 0.23 | ||
| Sesquiterpene hydrocarbons | 6.98 | 4.93 | 7.32 | 9.91 | 6.22 | 3.43 | 2.61 | 5.59 | 4.76 | 5.97 | ||
| Oxygenated sesquiterpenoids | 79.01 | 79.22 | 82.20 | 78.72 | 83.22 | 80.56 | 82.65 | 82.72 | 83.24 | 80.14 | ||
- under 0.01%. a Retention index on Quadex 007-5MS column. b For abbreviations of samples see Table 1.