Table 5. Parameters, Standard Uncertainties (D), and Values of R2 for the Toth Adsorption Isotherm Model Fitted by the Adsorption Dataa.
| adsorbate | T (K) | qsat (mg/g) | K (kPa–1) | t | D | R2 |
|---|---|---|---|---|---|---|
| n-hexane | 288 | 393 | 269.08 | 0.286 | 1.06 | 0.992 |
| 298 | 304 | 139.81 | 0.344 | 1.13 | 0.997 | |
| 308 | 248 | 66.43 | 0.367 | 1.42 | 0.996 | |
| 318 | 204 | 34.40 | 0.418 | 1.44 | 0.997 | |
| cyclohexane | 288 | 256 | 3.72 | 0.690 | 1.06 | 0.993 |
| 298 | 217 | 2.40 | 0.856 | 0.97 | 0.994 | |
| 308 | 194 | 1.46 | 0.883 | 0.95 | 0.990 | |
| 318 | 161 | 0.61 | 0.930 | 0.83 | 0.994 | |
| 1-hexene | 288 | 451 | 23.12 | 0.295 | 1.11 | 0.997 |
| 298 | 394 | 13.23 | 0.301 | 1.37 | 0.995 | |
| 308 | 321 | 8.49 | 0.325 | 1.07 | 0.996 | |
| 318 | 260 | 5.19 | 0.343 | 0.93 | 0.998 | |
| 2-methylpentane | 288 | 251 | 303.69 | 0.305 | 1.07 | 0.995 |
| 298 | 231 | 143.12 | 0.338 | 1.56 | 0.992 | |
| 308 | 212 | 65.49 | 0.379 | 1.10 | 0.999 | |
| 318 | 180 | 30.48 | 0.500 | 1.12 | 0.993 | |
| 3-methylpentane | 288 | 282 | 359.50 | 0.296 | 1.21 | 0.997 |
| 298 | 257 | 161.10 | 0.327 | 1.40 | 0.996 | |
| 308 | 231 | 71.70 | 0.350 | 1.34 | 0.995 | |
| 318 | 215 | 30.05 | 0.363 | 0.95 | 0.997 | |
| 2,2-dimethylbutane | 288 | 218 | 296.77 | 0.324 | 1.52 | 0.997 |
| 298 | 201 | 127.69 | 0.343 | 1.58 | 0.999 | |
| 308 | 180 | 64.28 | 0.388 | 1.26 | 0.998 | |
| 318 | 162 | 35.30 | 0.412 | 0.93 | 0.996 | |
| acetone | 288 | 338 | 2.63 | 0.325 | 1.26 | 0.993 |
| 298 | 329 | 1.69 | 0.333 | 1.66 | 0.997 | |
| 308 | 275 | 1.35 | 0.342 | 1.47 | 0.997 | |
| 318 | 251 | 0.99 | 0.347 | 1.05 | 0.998 | |
| butanone | 288 | 270 | 2.94 | 0.447 | 1.16 | 0.993 |
| 298 | 253 | 2.11 | 0.461 | 0.91 | 0.998 | |
| 308 | 226 | 1.50 | 0.476 | 1.10 | 0.992 | |
| 318 | 190 | 1.27 | 0.498 | 1.12 | 0.993 | |
| 2-pentanone | 288 | 291 | 5.01 | 0.406 | 1.43 | 0.996 |
| 298 | 271 | 4.00 | 0.425 | 1.53 | 0.994 | |
| 308 | 230 | 2.91 | 0.458 | 1.55 | 0.995 | |
| 318 | 207 | 1.91 | 0.518 | 1.11 | 0.994 |
Standard uncertainties are u(T) = 0.1 K and u(P) = 0.026 kPa and standard uncertainties for the fitted model are given in the table.