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. Author manuscript; available in PMC: 2022 Feb 15.
Published in final edited form as: Coord Chem Rev. 2020 Oct 21;429:213615. doi: 10.1016/j.ccr.2020.213615

Table 1.

Oxidation reactions of various metalloporphyrin MOFs.

Entry Ref. MOF Linker Metal Node Porphyrin Centre Model Reaction Conditions Yield (%)

1 [46] PCN-222 Fe-TCPP Zr6O4OH4(COO)8(OH)4(H2O)4 Fe graphic file with name nihms-1666379-t0019.jpg
2 [50] PCN-224 M–TCPP–Cl Zr6O4OH4(COO)6(OH)6(H2O)6 Ni, Co, Fe graphic file with name nihms-1666379-t0020.jpg 42
3 [48] PCN-223 TCPP Zr6O4OH4(COO)12 Fe graphic file with name nihms-1666379-t0021.jpg 99
4 [54] PCN-600 M–TCPP Fe3O(COO)6OH Mn, Fe, Co, Ni, Cu graphic file with name nihms-1666379-t0022.jpg
5 [81] Fe-PMOF-3 Fe-TCPP [Fe(OH)O4]n6+ Fe graphic file with name nihms-1666379-t0023.jpg 61
6 [82] Hf-PCN-222 Fe-TCCP-Cl Hf6O4OH4(COO)8(OH)4(H2O)4 Fe graphic file with name nihms-1666379-t0024.jpg 90
7 [88] NUPF-2Y TCPP [Y9OH12O2(COO)12] Fe graphic file with name nihms-1666379-t0025.jpg 96
8 [92] MMPF-3 Co-dcdbp [Co22-H2O)(H2O)4]3(COO)12 Co graphic file with name nihms-1666379-t0026.jpg 95.7
9 [94] MMPF-20 Ni-dcdbp [Ni3(COO)8]+ Ni graphic file with name nihms-1666379-t0027.jpg 55
10 [63] ZJU-18 Mn-OCPP [Mn5Cl2(COO)4]9+ Mn graphic file with name nihms-1666379-t0028.jpg >99
11 [78] In-Co(TBP)-MOF In-TBP, Co-TBP [In(COO)4] In-Co graphic file with name nihms-1666379-t0029.jpg 100
12 [91] ZnMnRPM Zn-TCPP,Mn-porphyrin-Cl Zn4O(COO)6 Zn-Mn graphic file with name nihms-1666379-t0030.jpg >60