Table 1.
Oxidation reactions of various metalloporphyrin MOFs.
Entry | Ref. | MOF | Linker | Metal Node | Porphyrin Centre | Model Reaction Conditions | Yield (%) |
---|---|---|---|---|---|---|---|
1 | [46] | PCN-222 | Fe-TCPP | Zr6O4OH4(COO−)8(OH)4(H2O)4 | Fe | ![]() |
– |
2 | [50] | PCN-224 | M–TCPP–Cl | Zr6O4OH4(COO−)6(OH)6(H2O)6 | Ni, Co, Fe | ![]() |
42 |
3 | [48] | PCN-223 | TCPP | Zr6O4OH4(COO−)12 | Fe | ![]() |
99 |
4 | [54] | PCN-600 | M–TCPP | Fe3O(COO−)6OH | Mn, Fe, Co, Ni, Cu | ![]() |
– |
5 | [81] | Fe-PMOF-3 | Fe-TCPP | Fe | ![]() |
61 | |
6 | [82] | Hf-PCN-222 | Fe-TCCP-Cl | Hf6O4OH4(COO−)8(OH)4(H2O)4 | Fe | ![]() |
90 |
7 | [88] | NUPF-2Y | TCPP | [Y9OH12O2(COO−)12]− | Fe | ![]() |
96 |
8 | [92] | MMPF-3 | Co-dcdbp | [Co2(μ2-H2O)(H2O)4]3(COO−)12 | Co | ![]() |
95.7 |
9 | [94] | MMPF-20 | Ni-dcdbp | [Ni3(COO−)8]+ | Ni | ![]() |
55 |
10 | [63] | ZJU-18 | Mn-OCPP | [Mn5Cl2(COO−)4]9+ | Mn | ![]() |
>99 |
11 | [78] | In-Co(TBP)-MOF | In-TBP, Co-TBP | [In(COO−)4]− | In-Co | ![]() |
100 |
12 | [91] | ZnMnRPM | Zn-TCPP,Mn-porphyrin-Cl | Zn4O(COO−)6 | Zn-Mn | ![]() |
>60 |