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. Author manuscript; available in PMC: 2022 Feb 15.
Published in final edited form as: Coord Chem Rev. 2020 Oct 21;429:213615. doi: 10.1016/j.ccr.2020.213615

Table 2.

Oxygen evolution reaction performance of porphyrin MOFs.

MOF electrocatalyst Over potential (η; V) Current density (mA/cm2) Electrolyte pH Ref.

PCN-224-fbb1,c 0.68a 0.15 0.1 M NaClO4 7 [178]
PCN-224(Ni)b1 0.68a 1 0.1 M NaClO4 7
PCN-224(Co)b2 0.860 2 Borate bufferedsolution 9.2 [182]
PCN-224(Co)b2 0.510 2 Borate-buffered solution 9.2
MWCNT 0.860a 10
Pb-TCPPb3 0.470 10 1.0 M KOH 14 [183]
Co-CuTCPP/rGOb3,d 0.396 10 1.0 M KOH 14 [184]
a

data approximated from the cyclic voltammetry (CV) and linear sweep voltammetry (LSV) voltammogram figures

b

scan rate 1 = 100 mV/s; 2 = 50 mV/s; 3 = 5 mV/s

c

free base (non-metalated) porphyrin

d

rGO = reduced graphene oxide