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. Author manuscript; available in PMC: 2022 Feb 15.
Published in final edited form as: Coord Chem Rev. 2020 Oct 21;429:213615. doi: 10.1016/j.ccr.2020.213615

Table 4.

Summary of CO2RR MOF catalysts.

Catalyst Overpotential (η; V) Current density(mA/cm2) Faradaic Efficiency (%) TOF(h−1) Solventa Refs.
MOF-525(Fe) 0.650 5.9 FECO = 40 FEH2 = 60 475 1 M TFE in MeCN [167]
MOF-525(Fe) 0.650 2.3 FECO = 54 FEH2 = 45 64 MeCN
Al2(OH)2TCPP(Co) 0.594 1 FECO = 76 200 0.5 M K2CO3 [197]
PCN-222(Fe)/C 0.494 1.2 FECO = 91 50 0.5 M KHCO3 [195]
Cu2(CuTCPP) 0.350 4.5 FEHCOO = 68.4 FECH3COO = 16.8 2185 1 M H2O / 0.5 MEMIMBF4 in MeCN [196]
a

TFE = trifluoroethanol; EMIM = 1-ethyl-3-methylimidazolium