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. 2016 Aug 10;8(8):292. doi: 10.3390/polym8080292

Table 1.

This table describes the attenuated total reflection infrared spectroscopy (ATR-FTIR) spectra and its corresponding bonds: their values and where they come from.

Band, cm−1 Bond Coming from
3,378 cm−1 N–H hydrogen bond stretching Isocyanates group
1,525 cm−1 C–N stretching and N–H bending Urethane group
3,492 cm−1 NCO groups Isocyanates group
1,637 cm−1 carbon double bonds modified PCL
814 cm−1 carbon double bonds modified PCL
1,722 cm−1 carbonyl absorption in crystalline PCL
1,455 cm−1 associated with the gauche isomer The methylene groups in the amorphous regions
1,600–900cm-1 chain conformation vibration of the methylene and ester groups