Table 4.
Activation energy of Fuyu oil Shale pyrolysis in air at the second stage.
| α/% | KAS | FWO | Friedman | ||||||
|---|---|---|---|---|---|---|---|---|---|
| E/kJ·mol−1 | A | R | E/kJ·mol−1 | A | R | E/kJ·mol−1 | A | R | |
| 10 | 116.529 | 1.95E+11 | 0.9816 | 129.166 | 2.44E+12 | 0.9885 | 152.570 | 1.06E+16 | 0.9766 |
| 20 | 110.992 | 1.87E+11 | 0.9903 | 115.788 | 2.43E+12 | 0.9939 | 136.923 | 1.03E+16 | 0.9465 |
| 30 | 100.217 | 1.88E+11 | 0.9932 | 106.176 | 2.26E+12 | 0.9944 | 101.447 | 1.03E+16 | 0.9550 |
| 40 | 106.328 | 1.99E+11 | 0.9829 | 112.422 | 2.43E+12 | 0.9859 | 132.874 | 1.14E+16 | 0.9746 |
| 50 | 119.979 | 1.93E+11 | 0.9894 | 125.775 | 2.52E+12 | 0.9911 | 149.153 | 0.97E+16 | 0.9420 |
| 60 | 126.872 | 1.92E+11 | 0.9898 | 132.649 | 2.41E+12 | 0.9914 | 152.961 | 1.05E+16 | 0.9547 |
| 70 | 136.790 | 1.89E+11 | 0.9977 | 142.390 | 2.36E+12 | 0.9980 | 161.349 | 1.11E+16 | 0.9973 |
| 80 | 151.381 | 1.93E+11 | 0.9941 | 154.735 | 2.47E+12 | 0.9949 | 194.797 | 1.10E+16 | 0.9467 |
| 90 | 266.821 | 1.95E+11 | 0.9838 | 269.281 | 2.43E+12 | 0.9836 | 456.414 | 1.06E+16 | 0.9717 |