Table 2. Selected geometric parameters (Å) for Ag3Sc2(PO4)3 at different temperatures.
| T = 100 K | |||
| Sc1—O4i | 2.035 (5) | P2—O2iv | 1.513 (4) |
| Sc1—O2i | 2.038 (4) | P2—O6 | 1.554 (4) |
| Sc1—O3 | 2.071 (4) | Ag1⋯Ag1B | 0.61 (7) |
| Sc1—O5ii | 2.089 (4) | Ag1⋯Ag1A | 0.70 (3) |
| Sc1—O1 | 2.141 (4) | Ag1A⋯Ag1A iii | 1.71 (5) |
| Sc1—O6 | 2.150 (4) | Ag1A⋯Ag3B v | 2.27 (2) |
| P1—O5iii | 1.514 (4) | Ag1B⋯Ag3A | 1.19 (7) |
| P1—O3 | 1.527 (4) | Ag2⋯Ag2A | 0.98 (6) |
| P1—O4 | 1.539 (5) | Ag3A⋯Ag3B | 1.30 (3) |
| P1—O1iv | 1.554 (4) | ||
| T = 200 K | |||
| Sc1—O5 | 2.045 (4) | P4—O13 | 1.522 (4) |
| Sc1—O13 | 2.049 (4) | P4—O14 | 1.547 (4) |
| Sc1—O8vi | 2.052 (4) | P5—O17 | 1.524 (4) |
| Sc1—O9 | 2.124 (4) | P5—O16 | 1.525 (4) |
| Sc1—O15 | 2.133 (3) | P5—O15 | 1.535 (4) |
| Sc1—O1 | 2.136 (4) | P5—O18 | 1.537 (4) |
| Sc2—O2i | 2.044 (3) | Ag1A⋯Ag1B | 0.628 (6) |
| Sc2—O16vii | 2.047 (4) | Ag1A⋯Ag6B x | 2.800 (15) |
| Sc2—O10viii | 2.051 (4) | Ag1B⋯Ag7C | 2.748 (18) |
| Sc2—O3ix | 2.126 (4) | Ag1B⋯Ag7B | 2.977 (14) |
| Sc2—O12x | 2.132 (3) | Ag2A⋯Ag2B | 0.620 (5) |
| Sc2—O18 | 2.135 (3) | Ag2A⋯Ag6C | 2.906 (14) |
| Sc3—O11x | 2.047 (4) | Ag2B⋯Ag7B viii | 2.632 (17) |
| Sc3—O4 | 2.048 (4) | Ag2B⋯Ag7A viii | 2.837 (15) |
| Sc3—O17xi | 2.052 (4) | Ag3A⋯Ag3B | 0.607 (6) |
| Sc3—O14xii | 2.124 (3) | Ag3A⋯Ag6A | 2.865 (10) |
| Sc3—O6vi | 2.127 (4) | Ag3B⋯Ag7A | 2.654 (11) |
| Sc3—O7x | 2.129 (4) | Ag3B⋯Ag7C viii | 2.977 (10) |
| P1—O4 | 1.527 (5) | Ag4⋯Ag4vi | 0.564 (13) |
| P1—O2 | 1.534 (4) | Ag4⋯Ag6A | 2.812 (11) |
| P1—O1 | 1.540 (4) | Ag5A⋯Ag5B | 0.628 (4) |
| P1—O3 | 1.543 (4) | Ag5A⋯Ag6B xiii | 2.862 (14) |
| P2—O8 | 1.525 (4) | Ag5B⋯Ag6C | 2.822 (17) |
| P2—O5 | 1.533 (4) | Ag6A⋯Ag6C xi | 0.897 (9) |
| P2—O7 | 1.536 (4) | Ag6A⋯Ag6B xi | 0.981 (7) |
| P2—O6 | 1.541 (4) | Ag6B⋯Ag6C | 0.899 (7) |
| P3—O10 | 1.526 (4) | Ag7A⋯Ag7B | 0.695 (9) |
| P3—O11 | 1.536 (4) | Ag7A⋯Ag7C viii | 0.704 (9) |
| P3—O9 | 1.538 (4) | Ag7B⋯Ag7C | 0.674 (9) |
| P3—O12 | 1.541 (3) | ||
| T = 300 K | |||
| Sc1—O1xi | 2.0505 (12) | Ag11⋯Ag11xv | 0.668 (3) |
| Sc1—O2 | 2.1324 (11) | Ag11⋯Ag21 | 1.35 (3) |
| P1—O1xi | 1.5261 (12) | Ag21⋯Ag22 | 1.18 (3) |
| P1—O2xiv | 1.5398 (11) | Ag22⋯Ag2 | 0.501 (12) |
| T = 520 K | |||
| Sc1—O1xi | 2.0542 (14) | Ag11⋯Ag11xv | 0.748 (3) |
| Sc1—O2 | 2.1334 (13) | Ag11⋯Ag21 | 1.310 (19) |
| P1—O1xi | 1.5215 (14) | Ag21⋯Ag22 | 1.03 (2) |
| P1—O2xiv | 1.5360 (14) | Ag22⋯Ag2 | 0.623 (11) |
Symmetry codes: (i) −x + 
, −y + , −z; (ii) −x, y, −z + ; (iii) −x + , −y + , −z + 1; (iv) −x + , y + , −z + ; (v) x, −y, z + ; (vi) −x + 1, y, −z + ; (vii) −x + , −y + 
, −z; (viii) −x + 1, −y + 1, −z; (ix) x − , y + , z; (x) x − , y − , z; (xi) x, y − 1, z; (xii) −x + 1, y − 1, −z + ; (xiii) −x + , y − , −z + ; (xiv) −x + 
, −y + 
, −z + ; (xv) x − y, x, −z.