TABLE 2.
Position |
1 |
18 |
19 |
|||
δ C | δ H (J in Hz)a | δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | |
1 | 126.5, C | 125.7, C | 125.7, C | |||
2 | 115.0, CH | 6.88, d (1.8) | 118.6, CH | 6.75, d (2.0) | 118.6, CH | 6.74, d (2.0) |
3 | 148.2, C | 143.8, C | 143.7, C | |||
4 | 146.7, C | 144.3, C | 144.2, C | |||
5 | 112.5, CH | 6.96, d (8.3) | 114.8, CH | 6.71, d (8.0) | 114.8, CH | 6.71, d (8.0) |
6 | 123.1, CH | 6.82, dd (8.3, 1.8) | 122.0, CH | 6.60, dd (8.0, 2.0) | 122.0, CH | 6.59, dd (8.0, 1.9) |
1′ | 117.7, C | 116.0, C | 115.8, C | |||
2′ | 148.3, C | 145.0, C | 144.9, C | |||
3′ | 139.5, C | 134.4, C | 134.4, C | |||
4′ | 132.7, C | 129.6, C | 130.1, C | |||
5′ | 103.2, CH | 6.46, s | 106.5, CH | 6.26, s | 106.5, CH | 6.24, s |
6′ | 153.2, C | 148.2, C | 148.1, C | |||
1″ | 138.2, C | 128.2, C | 128.2, C | |||
2″ | 128.7, CH | 7.61, d (7.5) | 130.0, CH | 7.35, d (8.5) | 116.6, CH | 6.97, d (2.0) |
3″ | 128.4, CH | 7.47, t (7.5) | 114.9, CH | 6.79, d (8.5) | 144.7, C | |
4″ | 127.3, CH | 7.37, t (7.5) | 156.2, C | 144.2, C | ||
5″ | 128.4, CH | 7.47, t (7.5) | 114.9, CH | 6.79, d (8.5) | 115.3, CH | 6.75, d (8.0) |
6″ | 128.7, CH | 7.61, d (7.5) | 130.0, CH | 7.35, d (8.5) | 119.9, CH | 6.79, dd (8.0, 2.0) |
1″′ | 64.8, CH2 | 4.53, d (6.7) | ||||
2″′ | 120.4, CH | 5.47, t (6.7) | ||||
3″′ | 136.9, C | |||||
4″′ | 18.0, CH3 | 1.72, s | ||||
5″′ | 25.5, CH3 | 1.76, s | ||||
3-OMe | 55.5, CH3 | 3.73, s | ||||
3′-OMe | 60.4, CH3 | 3.30, s | ||||
6′-OMe | 55.7, CH3 | 3.67, s | ||||
2′-OH | 8.68, s |
ad, dd, s, t respectively means doublet, a doublet of doublets, singlet and triplet.