Table 2.
Comparison of catalytic activity in alcohol oxidation reaction with previously reported catalysts.
| Entry | Catalyst | Catalyst amount | Condition | Time (h) | Yield (%) | Ref. |
|---|---|---|---|---|---|---|
| 1 | Cu-MOF-2 | 17 mol% | CH3CN/O2/75°C | 16 | 99 | [43] |
| 2 | UiO-66-Sal-CuCl2 | 4 mol% | CH3CN/O2/60°C | 24 | 99 | [47] |
| 3 | [Co3L(PTA)2.5(OAc)]b | 2 mol% | CH3CN/TBHP/60°C | 24 | 88 | [48] |
| 4 | [{Cu(L1)- (DMF)}·DMF·H2O]na | 0.2 mol% | MW/TBHP/100°C | 0.5 | 81.1 | [48] |
| 5 | Cu3(BTC)2 | 5 mol% | CH3CN/O2/70°C | 9 | 94 | [49] |
| 6 | Au@Cu(II)-MOF | 3 mol% | Toluene/air/110°C | 15 | 98 | [50] |
| 7 | Cu-MOF-74 | 2.5 mol% | CH3CN/O2/70°C | 12 | 89 | [51] |
| 8 | SPS–Cu (II)@Cu3(BTC)2 | 2 mol% | CH3CN/O2/75°C | 8 | 99 | [52] |
| 9 | Pd@Cu(II)- MOF | 5 mol% | Xylene/air/130°C | 25 | 95 | [53] |
| 10 | MIL-53(Fe)-graphene | 15 mol% | CCl4/visible light | 9 | 80 | [54] |
| 11 | Synthesized nanoscale Cu (II) complex | 1 mol% | SF/TBHP/rt | 0.5 | 98 | This work |
aPTA, p-phthalic acid; bL1, 5-{(pyridin-4-ylmethyl)amino} isophthalic acid.