Table 1. U/Pb CA-TIMS isotopic data Pb/U.
Sample | LA-ICPMS | Radiogenic Isotope Ratios | Isotopic Dates | ||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
206Pb* × 10−13 mol | mol % 206Pb* | * | Pbc (pg) | % err | % err | % err | corr. coef. | ± | ± | ± | |||||||||||
(a) | label | (b) | (c) | (c) | (c) | (c) | (d) | (e) | (e) | (f) | (e) | (f) | (e) | (f) | (g) | (f) | (g) | (f) | (g) | (f) | |
MHL-Cox 2 | |||||||||||||||||||||
z1 | 144 | 0.971 | 0.2723 | 99.25% | 44.5 | 0.17 | 2392 | 0.311 | 0.047845 | 0.303 | 0.094027 | 0.321 | 0.014260 | 0.053 | 0.422 | 90.54 | 7.18 | 91.25 | 0.28 | 91.275 | 0.048 |
z2 | 145 | 0.513 | 0.2190 | 99.45% | 54.5 | 0.10 | 3279 | 0.164 | 0.048009 | 0.226 | 0.093912 | 0.244 | 0.014194 | 0.045 | 0.496 | 98.63 | 5.33 | 91.14 | 0.21 | 90.855 | 0.040 |
MHM-Cox 3 | |||||||||||||||||||||
z1 | 262 | 0.438 | 0.3606 | 99.52% | 61.7 | 0.14 | 3789 | 0.140 | 0.048001 | 0.198 | 0.102478 | 0.210 | 0.015491 | 0.051 | 0.343 | 98.25 | 4.69 | 99.06 | 0.20 | 99.095 | 0.051 |
z2 | 263 | 1.472 | 0.2384 | 99.49% | 74.4 | 0.10 | 3566 | 0.471 | 0.047968 | 0.229 | 0.094457 | 0.248 | 0,014288 | 0.047 | 0.483 | 96.65 | 5.43 | 91.65 | 0.22 | 91.454 | 0.043 |
MHU-Cox 4 | |||||||||||||||||||||
z2 | 33 | 0.503 | 0.1096 | 98.88% | 26.6 | 0.10 | 1618 | 0.161 | 0.048049 | 1.003 | 0.097621 | 1.064 | 0.014742 | 0.152 | 0.464 | 100.64 | 23.71 | 94.58 | 0.96 | 94.338 | 0.142 |
z1a | 17 | 0.562 | 0.0828 | 98.15% | 16.2 | 0.13 | 978 | 0.180 | 0.047993 | 0.755 | 0.091585 | 0.796 | 0.013847 | 0.084 | 0.525 | 97.87 | 17.86 | 88.98 | 0.68 | 88.648 | 0.074 |
z1b | 17 | 0.627 | 0.0767 | 89.79% | 2.7 | 0.72 | 177 | 0.201 | 0.048354 | 2.643 | 0.092014 | 2.779 | 0.013808 | 0.326 | 0.465 | 115.55 | 62.31 | 89.38 | 2.38 | 88.401 | 0.286 |
Notes:
(a) z1, z2, etc. are labels for analyses composed of single zircon grains that were annealed and chemically abraded (Mattinson, 2005). z1a and z1b are fragments from the same grain.
(b) Model Th/U ratio calculated from radiogenic 208Pb/206Pb ratio and 207Pb/235U date.
(c) Pb* and Pbc are radiogenic and common Pb, respectively. mol % 206Pb* is with respect to radiogenic and blank Pb.
(d) Measured ratio corrected for spike and fractionation only. Fractionation correction for single-collector Daly analyses is based on measurement of 202Pb/205Pb in the EARTHTIME ET2535 tracer solution.
(e) Corrected for fractionation and spike. Common Pb in zircon analyses is assigned to procedural blank with composition of 206Pb/204Pb = 18.04 ± 0.61%; 207Pb/204Pb = 15.54 ± 0.52%; 208Pb/204Pb = 37.69 ± 0.63% (1 sigma). 206Pb/238U and 207Pb/206Pb ratios corrected for initial disequilibrium in 230Th/238U using a D(Th/U) of 0.20 ± 0.05 (1 sigma).
(f) Errors are 2 sigma, propagated using algorithms of Schmitz & Schoene (2007) and Crowley, Schoene & Bowring (2007).
(g) Calculations based on the decay constants of Jaffey et al. (1971). 206Pb/238U and 207Pb/206Pb dates corrected for initial disequilibrium in 230Th/238U using a D(Th/U) of 0.20 ± 0.05 (1 sigma).