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. 2021 Feb 27;26(5):1286. doi: 10.3390/molecules26051286

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© 2021 by the authors.

Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

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View of the [Rh(L¹)Cl₂]⁺ complex cation in [Rh(L¹)Cl₂](PF₆) with the numbering scheme adopted. Displacement ellipsoids are drawn at a 30% probability level. H-atoms are omitted for clarity. Selected bond distances (Å): Rh1-N1 2.015(3), Rh1-O1 2.088(2), Rh1-S1 2.2851(10), Rh1-S2 2.3056(10), Rh1-Cl1 2.3318(11), Rh1-Cl2 2.3001(10); angles (°): N1-Rh1-O1 89.92(11), N1-Rh1-S1 87.20(8), N1-Rh1-S2 86.48(8), N1-Rh1-Cl1 177.55(9), N1-Rh1-Cl2 89.96(9), S1-Rh1-O1 86.60(7), S1-Rh1-Cl1 91.94(4), S1-Rh1-Cl2 92.57(4), S1-Rh1-S2 170.23(3), S2-Rh1-O1 85.96(7), S2-Rh1-Cl1 94.07(4), S2-Rh1-Cl2 94.86(4), O1-Rh1-Cl1 87.74(8), O1-Rh1-Cl2 179.16(7), Cl1-Rh1-Cl2 92.37(4).