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Partial view along the [100] direction of [Rh(L1)Cl2]+ complex cations joined head to tail via C-H···Cl bonds to form zig-zag chains running along the [010] direction in [Rh(L1)Cl2](PF6). Only H atoms involved in the relevant H-bonds are shown for clarity. Cl1···H7Ai 2.66, Cl1···C7i 3.567(4) Å, Cl1-H7Ai···C7i 157°. Symmetry code: i = −x, −½ + y, 3/2 − z.
