View of the [Rh(L3)Cl2]+ complex cation in [Rh(L3)Cl2](BF4)·MeCN with the numbering scheme adopted. Displacement ellipsoids are drawn at a 30% probability level. H-atoms are omitted for clarity. Selected bond distances (Å): Rh1-N1 2.018(5), Rh1-N2 2.047(5), Rh1-S1 2.3124(15), Rh1-S2 2.3010(15), Rh1-Cl1 2.3511(15), Rh1-Cl2 2.3515(14); angles (°): N1-Rh1-N2 91.72(19), N1-Rh1-S1 86.99(15), N1-Rh1-S2 87.20(15), N1-Rh1-Cl1 178.94(14), N1-Rh1-Cl2 88.24(14), S1-Rh1-N2 87.20(15), S1-Rh1-Cl1 93.31(6), S1-Rh1-Cl2 92.94(6), S1-Rh1-S2 171.78(5), S2-Rh1-N2 87.17(15), S2-Rh1-Cl1 92.40(6), S2-Rh1-Cl2 92.68(6), N2-Rh1-Cl1 87.29(14), N2-Rh1-Cl2 179.84(17), Cl1-Rh1-Cl2 92.76(5).