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. 2021 Feb 27;26(5):1286. doi: 10.3390/molecules26051286

Figure 11.

Figure 11

(a) Partial view of head-to-head interacting [Rh(L3)Cl2]+ complex cations in [Rh(L3)Cl2](BF4)·MeCN to form chains running along the [100] direction: N2-H2···Cl2i 2.45 Å, N2···Cl2i 3.235(5) Å, N2-H2···Cl2i 142°; (b) partial view along the [101] direction of an undulated sheet lying in the (101) plane and formed by weak soft-soft interactions between [Rh(L3)Cl2]+ complex cations: Cl2···S2ii 3.478(2), Cl2···S1iii 3.483(2) Å. Symmetry codes: i = −1 + x, y, z; ii = ½ + x, ½ − y, ½ + z; iii = ½ + x, ½ − y, − ½ + z; iv = 1 + x, y, z.