TABLE 1.

Phenolic compounds detected in BerriQi® (µg/mL)

Peak	M+	(M‐H)‐	Compound	µg/mL	µg/g DW
			Anthocyanins
1	611		Cyanidin 3‐O‐sophoroside	883	937
2	449		Cyanidin 3‐O‐glucoside	571	606
3	481		Cyanidin 3‐O‐sambubioside	24	25
4	757		Cyanidin 3‐O‐(2‐glucosylrutinoside)	411	436
5	595		Cyanidin 3‐O‐rutinoside	62	66
6	727		Cyanidin 3‐O‐xylosylrutinoside	18	20
			Phenolic acids
7		169	Gallic acid	140	149
8		153	Protocatechuic acid	35	37
10		353	Chlorogenic acid	69	73
11		179	Caffeic acid	7	7
15		337	4‐p‐Coumaroylquinic acid	26	28
17		337	5‐p‐Coumaroylquinic acid	3	3
			Flavan−3‐ols and procyanidins
9		335 a	Catechin	3	3
12		577	Procyanidin B2	6	6
13		335 a	Epicatechin	21	22
25		579	Unknown procyanidin isomer	3	3
			Hydrolyzable tannins
14		1567	Sanguiin H10 isomer 1	9	10
16		469	Sanguisorbic acid dilactone	120	127
19		2036.5	Galloyl‐SH6	66	70
20		1567	Sanguiin H10 isomer 2	61	65
21		2501	Lambertian C (minus ellagic acid)	11	12
22		2803	Lambertian C	17	18
24		1869	Sanguiin H6	213	226
26		301	Ellagic acid	449	477
			Flavonols
27		609	Quercetin 3‐O‐rutinoside	6	6
28		463	Quercetin 3‐O‐galactoside	17	18
29		477	Quercetin 3‐O‐glucuronide	36	38
30		463	Quercetin 3‐O‐glucoside	13	14
31		433	Quercetin 3‐O‐pentoside 1	9	10
32		433	Quercetin 3‐O‐pentoside 3	6	6
33		433	Quercetin 3‐O‐pentoside 2	13	14
35		447	Quercetin 3‐O‐rhamnoside	15	16
37		301	Quercetin	19	20
			Chalcones
34		567	Phloretin 2‐O‐xylo‐glucoside	9	10
36		481 a	Phloretin 2‐O‐glucoside	62	66
			Unknowns
18		563 a	unknown	71	75
23		639	unknown	22	23
			Total	1557	1653

M⁺ and (M‐H)^‐ ions are the pseudomolecular ions used for identification of compounds by liquid chromatography‐mass spectrometry (LC‐MS). All identifications confirmed by MS/MSⁿ experiments. Peak numbers refer to chromatograms shown in supplementary data.

^aDetected as [M + formate]^‐ adduct.