Table 4.
Solution enthalpies of N-methylbutyrolactam, N-methylvalerolactam, N-methylcaprolactam in proton donor solvents (S), (kJ·mol−1, T = 298.15 K, P = 0.1 MPa) a.
Solvent (S) | N-methylbutyrolactam | N-methylvalerolactam | N-methylcaprolactam |
---|---|---|---|
Dichloromethane | −8.56 ± 0.05 | −8.33 ± 0.05 | −7.28 ± 0.04 |
Chloroform | −19.06 ± 0.09 | −19.29 ± 0.07 | −17.97 ± 0.05 |
a Standard uncertainties u are u(T) = 0.01 K, u(p) = 10 kPa. Uncertainties of solution enthalpies are calculated as a standard deviation of the mean.