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Molar ratio of reagents adopted for the synthesis of BUMA-based polymers.
| Sample | <dDLS> (nm) | Fox Tg (°C) | Real Tg (°C) |
|---|---|---|---|
| BUMA_MA | 180 ± 70 | 67.1 | n.d. |
| BUMA_MA_MMA | (85 ± 15); (250 ± 60) | 55.5 | 78.2 |
| BUMA_MA_MMA_T3 | 80 ± 20 | 55.5 | 75.2 |
| BUMA_MAC_25 | (37 ± 7); (170 ± 30) | 40.8 | 46.1 |
| BUMA_MAC_50 | (25 ± 4); (80 ± 10) | 71.1 | 51.0 |
| BUMA_MAC_75 | 12 ± 3 | 120.3 | n.d. |
