Table 3.
Adsorption isotherms and kinetic models constants and the corresponding error functions.
Isotherm model | Parameters | Value | Kinetic model | Parameters | Value |
---|---|---|---|---|---|
Langmuir | KL (L mg−1) | 0.331 ± 0.139 | Pseudo-first order | k1 (min−1) | 0.066 ± 0.001 |
qmax (mg g−1) | 1.508 ± 0.196 | qe,calc (mg g−1) | 0.419 ± 0.002 | ||
R2 | 0.9715 | R2 | 0.9996 | ||
χ2 | 2.62 × 10−1 | χ2 | 1.17 × 10−4 | ||
SSE | 4.52 × 10−2 | SSE | 3.73 × 10−5 | ||
ARE (%) | 43.95 | ARE (%) | 17.30 | ||
Freundlich | Kf (mg g−1) | 0.458 ± 0.017 | Pseudo-second order | k2 (g mg−1 min−1) | 0.122 ± 0.018 |
1/n | 0.372 ± 0.115 | qe,calc (mg g−1) | 0.535 ± 0.017 | ||
R2 | 0.9968 | R2 | 0.9971 | ||
χ2 | 0.75 × 10−2 | χ2 | 1.15 × 10−3 | ||
SSE | 0.2 × 10−2 | SSE | 3.46 × 10−4 | ||
ARE (%) | 4.25 | ARE (%) | 18.67 | ||
Sips | Qsat | 3.921 ± 1.081 | qe,exp (mg g−1) | 0.407 ± 0.021 | |
KF | 0.131 ± 0.041 | ||||
1/n | 2.109 ± 0.037 | ||||
R2 | 0.9993 | ||||
χ2 | 0.11 × 10−2 | ||||
SSE | 0.57 × 10−3 | ||||
ARE (%) | 2.39 |