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. Author manuscript; available in PMC: 2021 Mar 19.
Published in final edited form as: Int J Environ Anal Chem. 2015 Dec 21;96(1):15–37. doi: 10.1080/03067319.2015.1114104

Table 2.

Instrumental and detection limits for the XOS prototype analyzer and the Niton based on the analysis of an archived soil sample.

Element XOS prototype XRF Niton
IDL (mg/kg) MDL§ (mg/kg) IDL (mg/kg) MDL (mg/kg)
As 0.1 2 2.5 7
Cd 1.2 36 6.6 14
Hg 0.1 1 4.0 2
Pb 0.1 2 3.4 7
Ba 4.9 40 28 65
Co 0.2 6 18 4
Cr 0.8 7 14 14
Cu 0.1 17 10 22
Fe 0.2 45 23 64
Mn 0.4 37 37 85
Ni 0.2 2 35 5
Se 0.1 14 2.0 6
Sn 0.2 28 19 12
Sr 0.1 2 <1 3
Ti 2.3 54 25 12
V 1.4 9 17 13
Zn 0.1 34 5.1 23
§

n=9 days (triplicate within day)

n=5 days (triplicate within day)

IDL is instrument detection limit and is defined within the instrument software as “≤” and is based on the analysis of a SiO2 blank

MDL is method detection limit based on analysis of an archived soil sample. See text for details