Table 2.
Instrumental and detection limits for the XOS prototype analyzer and the Niton based on the analysis of an archived soil sample.
| Element | XOS prototype XRF | Niton | ||
|---|---|---|---|---|
| IDL (mg/kg) | MDL§ (mg/kg) | IDL (mg/kg) | MDL¶ (mg/kg) | |
| As | 0.1 | 2 | 2.5 | 7 |
| Cd | 1.2 | 36 | 6.6 | 14 |
| Hg | 0.1 | 1 | 4.0 | 2 |
| Pb | 0.1 | 2 | 3.4 | 7 |
| Ba | 4.9 | 40 | 28 | 65 |
| Co | 0.2 | 6 | 18 | 4 |
| Cr | 0.8 | 7 | 14 | 14 |
| Cu | 0.1 | 17 | 10 | 22 |
| Fe | 0.2 | 45 | 23 | 64 |
| Mn | 0.4 | 37 | 37 | 85 |
| Ni | 0.2 | 2 | 35 | 5 |
| Se | 0.1 | 14 | 2.0 | 6 |
| Sn | 0.2 | 28 | 19 | 12 |
| Sr | 0.1 | 2 | <1 | 3 |
| Ti | 2.3 | 54 | 25 | 12 |
| V | 1.4 | 9 | 17 | 13 |
| Zn | 0.1 | 34 | 5.1 | 23 |
n=9 days (triplicate within day)
n=5 days (triplicate within day)
IDL is instrument detection limit and is defined within the instrument software as “≤” and is based on the analysis of a SiO2 blank
MDL is method detection limit based on analysis of an archived soil sample. See text for details