Table 5.

Results obtained by ICP-OES (n=1) and XRF (n=3, mean (SD)) for a representative number of CPs and ES samples; blank results indicate result <MDL by ICP-OES or <IDL by XRF methods. Units are mg/kg, except where indicated.

Type Name, Manufacturer Origin	CP Personal Kajal, Blue Heaven Cosmetics Ltd. India			CP Kohl Aswad, Hashmi Pakistan			CP Surmi Special, Hasmi Pakistan
Method	ICP-OES	XOS prototype	Niton	ICP-OES	XOS prototype	Niton	ICP-OES	XOS prototype	Niton
As					0.04 (0.04)%	8.7 (0.34)%	7.2	359 (34)	8.2 (0.11)%
Cd		10 (13)		13	1.1 (0.9)	1.1 (0.17)%	16	0.4 (0.2)	2.6 (2.4)%
Hg				3.7			2.5
Pb	25	3 (2)		20%	4.9 (2.9)%	>100 (2.3)%	19%	3.0 (0.09)%	>100 (0.61)%
Ba	2.5			60	192 (<1)	5.1 (0.84)%	96		12 (11)%
Co	2.6	38 (<1)		0.3	3 (<1)		2.2	21 (<1)
Cr	3.9	14 (15)		0.4	18 (<1)		1.1
Cu	3.3	3 (<1)		348	41 (20)	713 (116)	0.16%	0.02 (0.002)%	0.6 (0.04)%
Fe	2.8%	1.0 (0.9)%	6.6 (0.76)%	213	112 (22)		720	108 (9)
Mn	190	84 (99)	319 (56)	1.4			15.4
Ni	4.0	5 (6)		0.8	15 (<1)		1.8
Se		0.2 (0.1)		0.9	81 (<1)
Sn		34 (58)			3 (2)	2.7 (0.48)%		1 (<1)	6.3 (5.7)%
Sr	0.8			109	246 (<1)		168
Ti	62	185 (301)		0.4	69 (<1)		0.4	6 (<1)
V		65 (83)		0.3	67 (<1)	44 (1)	0.3
Zn		6 (<1)		0.54%	0.08 (0.01)%	2.2 (0.04)%	0.55%	0.07 (0.004)%	2.5 (0.02)%
Type Name, Manufacturer Origin	CP Kajal powder Unknown			ES Chili powder India
Method	ICP-OES	XOS prototype	Niton	ICP-OES	XOS prototype	Niton
As		263 (176)	8.7 (0.40)%		6 (2)	14 (6)
Cd	37	0.6 (0.3)	1.7 (1.2)%		1 (<1)
Hg	3.2
Pb	20%	3.7 (0.60)%	>100 (4.5)%	193	218 (11)	261 (19)
Ba	162		7.9 (5.7)%	32	34 (12)
Co	0.5	4 (5)	897 (<1)	0.8	2 (<1)
Cr	0.5			47	54 (10)	84 (8)
Cu	152	7 (1)		11	12 (0.6)	17 (1)
Fe	605	68 (6)		228	295 (38)	273 (51)
Mn	7.3		0.16 (0.04)%	19	24 (3)
Ni	1.1			2	3 (<1)
Se		8 (2)			0.3 (0.1)
Sn		0.9 (0.2)	4.0 (2.8)%		20 (0.6)
Sr	193			13	13 (<1)	17 (0.5)
Ti	0.6	98 (48)		3.9	34 (10)	55 (10)
V	0.4	16 (19)		0.1	7 (1)
Zn	0.30%	385 (189)	1.5 (0.18)%	19	23 (2)	23 (3)