Table 3.
Summary of results (average values with standard deviations) for all measurands and samples according to the area of production (continental and coastal Croatia) and winegrowing zones (B, CI, and CII) in Croatia.
|
Measurand
(Unit) |
GLM-ANOVA (p < 0.05)a |
All samples (n = 190) |
Continental Croatia = Zone B + Zone CI (n = 120) |
Coastal Croatia = Zone CII (n = 70) |
Zone B (n = 78) |
Zone CI (n = 42) |
|---|---|---|---|---|---|---|
| δ18O (‰ SMOW) | 1, 2, 3, 4, 5, 6 | 1.37 ± 2.56 | −0.22 ± 1.47 | 4.09 ± 1.52 | −0.61 ± 1.44 | 0.51 ± 1.23 |
| δ13C (‰ V-PDB) | 2, 3, 5, 6 | −27.57 ± 1.47 | −28.31 ± 1.01 | −26.29 ± 1.24 | −28.38 ± 0.99 | −28.20 ± 1.06 |
| Al (mg L−1) | 1, 3, 5 | 0.59 ± 0.52 | 0.51 ± 0.42 | 0.74 ± 0.64 | 0.48 ± 0.39 | 0.56 ± 0.48 |
| As (μg L−1) | 7.5 ± 5.4 | 7.2 ± 5.1 | 8.2 ± 5.9 | 7.2 ± 5.0 | 7.2 ± 5.2 | |
| B (mg L−1) | 1, 3, 5, 6 | 2.98 ± 1.14 | 2.62 ± 1.03 | 3.60 ± 1.07 | 2.76 ± 0.97 | 2.36 ± 1.10 |
| Ba (mg L−1) | 6 | 0.11 ± 0.05 | 0.11 ± 0.05 | 0.10 ± 0.04 | 0.11 ± 0.05 | 0.12 ± 0.04 |
| Ca (mg L−1) | 1, 2, 3, 5 | 85.0 ± 22.7 | 89.3 ± 21.2 | 77.5 ± 23.6 | 92.1 ± 20.9 | 84.1 ± 20.9 |
| Cd (μg L−1) | 2 | 0.7 ± 1.0 | 0.7 ± 1.0 | 0.8 ± 0.8 | 0.7 ± 1.2 | 0.5 ± 0.7 |
| Co (μg L−1) | 2 | 5.9 ± 4.4 | 5.5 ± 3.9 | 6.6 ± 5.1 | 5.8 ± 4.4 | 4.9 ± 2.6 |
| Cr (μg L−1) | 2 | 19.0 ± 17.0 | 17.4 ± 12.0 | 21.8 ± 23.1 | 17.4 ± 11.8 | 17.4 ± 12.6 |
| Cu (mg L−1) | 0.18 ± 0.14 | 0.17 ± 0.15 | 0.18 ± 0.12 | 0.18 ± 0.17 | 0.16 ± 0.09 | |
| Fe (mg L−1) | 1 | 1.91 ± 1.39 | 1.86 ± 1.43 | 20.1 ± 1.34 | 1.78 ± 1.32 | 2.00 ± 1.61 |
| K (mg L−1) | 3, 5, 6 | 788 ± 226 | 730 ± 180 | 889 ± 260 | 730 ± 179 | 730 ± 185 |
| Li (μg L−1) | 3, 6 | 4.6 ± 3.2 | 5.2 ± 3.5 | 3.6 ± 2.3 | 4.7 ± 3.3 | 6.0 ± 3.6 |
| Mg (mg L−1) | 1, 4, 5 | 81.3 ± 17.9 | 79.8 ± 16.6 | 83.9 ± 19.8 | 76.8 ± 15.9 | 85.4 ± 16.5 |
| Mn (mg L−1) | 4, 6 | 0.96 ± 0.52 | 1.01 ± 0.58 | 0.87 ± 0.39 | 0.92 ± 0.63 | 1.19 ± 0.45 |
| Mo (μg L−1) | 2 | 4.3 ± 2.1 | 4.4 ± 2.2 | 4.1 ± 2.0 | 4.7 ± 2.3 | 4.0 ± 2.0 |
| Na (mg L−1) | 1, 3, 5, 6 | 14.3 ± 18.1 | 10.6 ± 7.0 | 20.8 ± 27.3 | 10.7 ± 7.9 | 10.2 ± 5.0 |
| Pb (μg L−1) | 1, 2, 3 | 30.2 ± 18.7 | 28.0 ± 17.2 | 33.8 ± 20.5 | 29.1 ± 16.5 | 26.1 ± 18.6 |
| Rb (mg L−1) | 3, 5, 6 | 1.08 ± 0.41 | 0.99 ± 0.42 | 1.22 ± 0.35 | 1.05 ± 0.43 | 0.88 ± 0.37 |
| Sn (μg L−1) | 2, 3, 5, 6 | 55.0 ± 30.3 | 48.4 ± 31.1 | 66.3 ± 25.3 | 46.8 ± 29.2 | 51.6 ± 34.6 |
| Sr (mg L−1) | 1 | 0.46 ± 0.21 | 0.46 ± 0.17 | 0.46 ± 0.28 | 0.46 ± 0.18 | 0.45 ± 0.15 |
| V (μg L−1) | 1 | 83.6 ± 16.8 | 82.4 ± 15.8 | 85.6 ± 18.3 | 80.0 ± 15.1 | 86.7 ± 16.2 |
| Zn (mg L−1) | 0.69 ± 0.37 | 0.67 ± 0.32 | 0.73 ± 0.44 | 0.69 ± 0.34 | 0.64 ± 0.27 |
a
Measurands with p < 0.05 for: (1)—type of production; (2)—harvest year; (3)—continental and coastal area; (4)—zones B and CI; (5)—zones B and CII; (6)—zones CI and CII.