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. 2020 Feb 19;59(18):6964–6974. doi: 10.1002/anie.201910767

Scheme 6.

Scheme 6

Stereoelectronic rationale behind the Baeyer–Villiger oxidation and recent examples of enantioinduction: A) Lewis acid catalyzed approach of Feng; B) organocatalyzed method of Ding using chiral phosphoric acids; C) transition‐metal‐catalyzed system of Stoltz; D) method of Yamamoto using a self‐assembled flavinium‐(DHQ)2PHAL ion pair. mCPBA=meta‐chloroperoxybenzoic acid, (DHQ)2PHAL=hydroquinine 1,4‐phthalazinediyl diether.