Figure 10.

Correlations of LB _B parameters with further types of experimental or quantum‐chemically calculated basicity descriptors (open data points not used for the construction of the correlation lines). a) Correlation of LB _B with experimental BF₃ affinities in dichloromethane (−ΔH ${}_{\mathrm{BF}{}_3}$ ) from ref. [5]. b) Correlation of LB _B with quantum‐chemically calculated BH₃ affinities BA (at the SMD(DCM)/MN15/def2‐TZVP level of theory, referenced to the experimental Δ_r G value of the reaction of 1 d with 2 d as outlined in the Supporting Information).