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. 2020 Dec 29;27(12):3892–3928. doi: 10.1002/chem.202003134

Scheme 22.

Scheme 22

Associative N2 protonation using iron complexes 111113 supported by chelating diphosphines (a), and resulting hydrazido complex 114, diazenido complex 115 and ammonia complex 116 (b). Iron complexes 117118 supported by chelating triphosphines and hydrides 119120 (c).