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Aminocarbonylation of indoles and their analogues with aromatic aminesa.
aReaction conditions: KAP-Pd-PEPPSI-3 (5 mol%), indole (0.25 mmol), amine (1.25 mmol), I2 (0.5 mmol), DABCO (0.5 mmol), CsF (1.0 mmol), CO (2.0 MPa), DMF (2.0 mL), 80 °C, 24 h, isolated yield.
