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(a) Kinetically-controlled adsorption (3.68) to an initially clean spherical surface. (b) Diffusion-controlled adsorption (3.71) to a spherical surface. Adsorption occurs over a faster time scale τd,s in smaller bubbles (Λd = Ld/R ≳ 1), and approaches equilibrium exponentially, rather than as in the case of large bubbles (Λd → 0).
