Table 1. A Summary of the Figures of Merit Used for Method Characterizationa.
| characteristic | description | FoM | interpretation | |
|---|---|---|---|---|
| accuracy | closeness of agreement between measurement results and the accepted reference values | total prediction error | ||
| trueness | difference between the expected measurement results and the accepted reference values | average of the residuals; systematic component of the total error (i.e., constant offset) | ||
| precision | closeness of agreement between independent measurement results obtained with the same method in different measurement facilities with different operators using different equipment | width of residuals distribution; random component of the total error |
x̂i and xi are the predicted and assigned reference values, respectively, for the test sample i, and N is the number of samples in the TEST set. Accuracy = reproducibility + trueness (RMSEP2 ≅ SEP2 + BIAS2), as from ISO 5725 (ref (39)).