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. 2020 Mar 17;33(4):967–974. doi: 10.1021/acs.chemrestox.9b00506

Table 2. Experimental Protonation Constant Values of DMSA in NaCl at I = 0.15 mol L–1.

  log βa
reaction 288.15 K 298.15 K 310.15 K 318.15 K
H+ + L4– = HL3– 10.96 ± 0.02 11.01 ± 0.04 11.27 ± 0.02 11.32 ± 0.03
2H+ + L4– = H2L2– 20.15 ± 0.03 20.32 ± 0.03 20.64 ± 0.02 20.82 ± 0.03
3H+ + L4– = H3L 23.51 ± 0.05 23.87 ± 0.02 24.35 ± 0.02 24.61 ± 0.02
4H+ + L4– = H4L0 26.14 ± 0.04 26.39 ± 0.03 26.85 ± 0.02 27.09 ± 0.02
a

±standard deviation.