Synthesis of tocopherols, plastoquinone and plastochromanol-8 in higher plants. The mutants of genes encoding enzymes of Arabidopsis are given in italics. DMPBQ, 2,3-dimethyl-6-phytyl-1,4-benzoquinone; HGA, homogentisic acid; HPP, p-hydroxyphenylpyruvate; HPPD, p-hydroxyphenylpyruvate dioxygenase; HPT, homogentisate phytyltransferase; HST, homogentisate solanesyl transferase; MPBQ, 2-methyl-6-phytyl-1,4-benzoquinone; MPBQ MT, 2-methyl-6-phytyl-1,4-benzoquinone methyltransferase; MSBQ, 2-methyl-6-solanesyl-1,4-benzoquinone; PC-8, plastochromanol-8; PQ-9, plastoquinone-9; PQH2-9, plastoquinol-9; PPP, phytyl pyrophosphate; SPP, solanesyl pyrophosphate; TAT, tyrosine aminotransferase; TC, tocopherol cyclase; γ-TMT, γ-tocopherol methyltransferase; α-Toc, α-tocopherol; β-Toc, β-tocopherol; γ-Toc, γ-tocopherol; δ-Toc, δ-tocopherol; Tyr, tyrosine.