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. 2021 Mar 18;19(3):162. doi: 10.3390/md19030162

Table 1.

¹H/¹³C NMR chemical shift assignments of Fr-2 (800 MHz, D₂O).

Residue.		Chemical Shift (ppm)
Residue.		H/C	1	2	3	4	5	6	7	8
T	→3)-β-d-anTal_4S6S-diol	H	4.983	3.949	4.523	4.952	4.433	4.263/4.119
T	→3)-β-d-anTal_4S6S-diol	C	91.58	85.93	79.13	79.79	80.38	70.6
U’	→4)-β-d-GlcA-(1→	H	4.484	3.623	3.673	3.893	3.673
U’	→4)-β-d-GlcA-(1→	C	103.64	76.38	79.79	78.13	79.32	177.34
A	→3)-β-d-GalNAc_4S6S-(1→	H	4.485	3.971	3.938	4.729	3.893	4.101/4.184
A	→3)-β-d-GalNAc_4S6S-(1→	C	102.58	54.05	78.9	79.05	74.53	69.88	177.76	25.3
F’ (I’)	α-l-Fuc_2S4S-(1→	H	5.602	4.403	4.064	4.766	4.817	1.276
F’ (I’)	α-l-Fuc_2S4S-(1→	C	99.3	77.88	67.27	83.62	69.04	18.53
F’ (II’)	α-l-Fuc_3S4S-(1→	H	5.261	3.857	4.422	4.942	4.783	1.303
F’ (II’)	α-l-Fuc_3S4S-(1→	C	101.85	69.18	77.75	81.92	68.89	18.8
F’(III’)	α-l-Fuc_4S-(1→	H	5.315	3.708	3.949	4.69	4.745	1.267
F’(III’)	α-l-Fuc_4S-(1→	C	102.04	71.33	71.46	83.94	68.98	18.47
U	d-GlcA-(1→	H	4.416	3.512	3.551	3.618	3.671
U	d-GlcA-(1→	C	106.4	76.63	84.19	72.6	79.32	177.76
F (I)	α-l-Fuc_2S4S-(1→	H	5.493	4.357	4.079	4.596	4.452	1.167
F (I)	α-l-Fuc_2S4S-(1→	C	99.17	77.88	69.18	83.83	68.89	18.35
F (II)	α-l-Fuc_3S4S-(1→	H	5.273	3.856	4.437	4.933	4.769	1.167
F (II)	α-l-Fuc_3S4S-(1→	C	101.55	69.1	78.06	82.13	69.1	18.5
F (III)	α-l-Fuc_4S-(1→	H	5.187	3.711	3.93	4.511	4.408	1.144
F (III)	α-l-Fuc_4S-(1→	C	101.19	71.33	71.46	83.55	68.98	18.35