Table 2.
PAH 1 (μg/kg) | ||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Roasting | BaA | CHR | BbF | BaP | PAH4 | |||||||||||
Temp. (°C) | Time (min) | Control | Cellulosic Aerogel | t-Value | Control | Cellulosic Aerogel | t-Value | Control | Cellulosic Aerogel | t-Value | Control | Cellulosic Aerogel | t-Value | Control | Cellulosic Aerogel | t-Value |
150 | 10 | 0.93 ± 0.01 bc | 0.64 ± 0.01 c | 35.10 *** | 0.41 ± 0.01 c | 0.30 ± 0.02 d | 10.18 *** | 0.18 ± 0.00 b | ND2 | - | 0.18 ± 0.00 b | ND | - | 1.71 ± 0.02 bB | 0.94 ± 0.01 dB | 48.98 *** |
20 | 0.91 ± 0.02 c | 0.64 ± 0.01 c | 19.98 *** | 0.42 ± 0.01 b | 0.27 ± 0.03 b | 7.73 ** | 0.17 ± 0.01 d | ND | - | 0.19 ± 0.01 b | ND | - | 1.69 ± 0.01 dB | 0.92 ± 0.04 dB | 36.47 *** | |
30 | 0.95 ± 0.02 c | 0.71 ± 0.01 d | 20.18 *** | 0.44 ± 0.02 d | 0.30 ± 0.01 d | 10.49 *** | 0.18 ± 0.01 c | ND | - | 0.19 ± 0.00 c | ND | - | 1.77 ± 0.03 cA | 1.01 ± 0.01 dA | 37.56 *** | |
180 | 10 | 0.91 ± 0.02 cB | 0.65 ± 0.01 bB | 17.82 *** | 0.46 ± 0.02 bC | 0.34 ± 0.02 cB | 7.97 ** | 0.19 ± 0.01 b | ND | - | 0.19 ± 0.01 ab | ND | - | 1.75 ± 0.00 bC | 1.00 ± 0.01 cC | 92.17 *** |
20 | 0.92 ± 0.01 cB | 0.66 ± 0.02 cB | 19.21 *** | 0.48 ± 0.01 bB | 0.30 ± 0.01 bC | 28.47 *** | 0.19 ± 0.01 c | 0.15 ± 0.01 | 4.42 * | 0.19 ± 0.01 b | ND | - | 1.78 ± 0.00 cB | 1.12 ± 0.03 cB | 40.60 *** | |
30 | 0.97 ± 0.02 cA | 0.76 ± 0.02 cA | 12.54 *** | 0.56 ± 0.01 cA | 0.42 ± 0.01 cA | 20.66 *** | 0.22 ± 0.02 c | 0.16 ± 0.01 | 5.26 ** | 0.20 ± 0.01 c | ND | - | 1.95 ± 0.02 bA | 1.34 ± 0.03 cA | 27.97 *** | |
210 | 10 | 1.13 ± 0.03 aB | 0.79 ± 0.01 aB | 16.98 *** | 0.47 ± 0.00 bB | 0.39 ± 0.01 bC | 9.76 *** | 0.21 ± 0.01 bC | 0.17 ± 0.01 | 5.35 ** | 0.20 ± 0.01 abB | ND | - | 2.00 ± 0.04 aC | 1.35 ± 0.02 aC | 24.48 *** |
20 | 1.13 ± 0.01 bB | 0.73 ± 0.02 bC | 41.72 *** | 0.59 ± 0.08 aA | 0.49 ± 0.01 aA | 2.12 | 0.25 ± 0.01 bB | 0.20 ± 0.01 B | 10.09 *** | 0.22 ± 0.02 aA | ND | - | 2.20 ± 0.06 bB | 1.43 ± 0.00 bB | 21.63 ** | |
30 | 1.80 ± 0.05 aA | 0.89 ± 0.01 aA | 30.76 *** | 0.62 ± 0.01 bA | 0.44 ± 0.01 bB | 21.06 *** | 0.30 ± 0.04 bA | 0.24 ± 0.01 A | 2.73 | 0.24 ± 0.01 bA | ND | - | 2.97 ± 0.05 aA | 1.58 ± 0.01 bA | 43.54 *** | |
240 | 10 | 0.97 ± 0.01 bC | 0.63 ± 0.01 cC | 34.20 *** | 0.53 ± 0.03 aC | 0.42 ± 0.01 aB | 5.67 * | 0.31 ± 0.02 aC | 0.20 ± 0.01 C | 7.33 ** | 0.20 ± 0.00 aB | ND | - | 2.02 ± 0.04 aC | 1.26 ± 0.03 bC | 27.48 *** |
20 | 1.27 ± 0.02 aB | 0.98 ± 0.02 aA | 18.17 *** | 0.61 ± 0.01 aB | 0.45 ± 0.03 aB | 10.01 | 0.45 ± 0.00 aB | 0.38 ± 0.01 B | 10.18 *** | 0.24 ± 0.01 aA | ND | - | 2.58 ± 0.02 aB | 1.82 ± 0.05 aB | 22.58 *** | |
30 | 1.30 ± 0.01 bA | 0.83 ± 0.02 bB | 43.52 *** | 0.72 ± 0.01 aA | 0.50 ± 0.01 aA | 26.30 *** | 0.55 ± 0.02 aA | 0.41 ± 0.01 A | 9.76 *** | 0.35 ± 0.02 aA | 0.22 ± 0.01 | 12.95 *** | 2.92 ± 0.03 aA | 1.97 ± 0.00 aA | 46.83 *** |
1 PAH: benzo[a]anthracene: BaA; chrysene: CHR; benzo[b]fluoranthene: BbF; benzo[a]pyrene: BaP; PAH4: the sum of BaA, CHR, BbF, and BaP; Control: untreated cellulosic aerogel; 2 ND: not detected, below the detection limit. a–d In each line, different letters indicate significant difference (p < 0.05) as a function of roasting temperature at the same roasting time and with the same sample by Duncan’s test. A–C In each line, different letters indicate significant difference (p < 0.05) as a function of roasting time at the same roasting temperature and with the same sample by Duncan’s test. Significant differences between the control and cellulosic aerogel-treated groups were analyzed by the t-test (* p < 0.05, ** p < 0.01, and *** p < 0.001).