Table 5.
Volatile (AU × 104/g of Cecina) | m/z | LRI | Control | Salt Mixture I | Salt Mixture II | SEM | Sig. |
---|---|---|---|---|---|---|---|
Cyclobutanol | 44 | 489 | 4.90 | 3.71 | 4.08 | 0.25 | ns |
Methanethiol | 48 | 492 | 1.37 a,b | 1.27 b | 1.73 a | 0.076 | * |
Propan-1-ol | 59 | 563 | 21.23 | 23.57 | 17.64 | 1.01 | ns |
2-methylpropan-1-ol | 43 | 643 | 5.90 | 5.19 | 6.69 | 0.31 | ns |
3-methylbutan-1-ol | 70 | 817 | 133.38 b | 168.32 a | 120.68 b | 7.22 | * |
2-methylbutan-1-ol | 57 | 821 | 36.36 | 33.30 | 29.34 | 1.69 | ns |
Pentan-1-ol | 70 | 859 | 20.35 | 16.81 | 20.39 | 1.01 | ns |
Propane-1,2-diol | 45 | 887 | 172.17 | 172.08 | 155.07 | 10.05 | ns |
Hexane-1,6-diol | 59 | 910 | 5.37 | 7.22 | 5.77 | 0.38 | ns |
Prop-2-en-1-ol | 57 | 933 | 79.92 b | 88.46 b | 130.14 a | 6.71 | ** |
Hexan-1-ol | 56 | 975 | 37.20 b | 22.30 c | 46.61 a | 2.27 | *** |
Furan-3-ylmethanol | 98 | 986 | 326.71 | 304.58 | 312.89 | 10.28 | ns |
Butane-1,2-diol | 59 | 995 | 22.78 b | 32.44 a | 26.29 a,b | 1.57 | * |
3-ethyl-4-methylpentan-1-ol | 69 | 1001 | 14.04 a | 17.28 a | 9.86 b | 0.85 | *** |
Oct-1-en-3-ol | 57 | 1079 | 151.20 | 126.29 | 119.37 | 7.08 | ns |
3-methylsulfanylpropan-1-ol | 106 | 1106 | 10.82 | 11.46 | 7.46 | 0.82 | ns |
Phenylmethanol | 108 | 1159 | 81.48 b | 94.45 a | 79.46 b | 2.64 | * |
4-methylphenol | 107 | 1218 | 41.53 | 42.15 | 37.13 | 1.60 | ns |
2-phenylethanol | 91 | 1221 | 139.83 | 150.49 | 109.50 | 9.02 | ns |
Undecan-1-ol | 97 | 1299 | 3.03 | 3.49 | 3.15 | 0.21 | ns |
2-methoxy-4-prop-2-enylphenol | 164 | 1394 | 3.33 | 4.09 | 2.99 | 0.28 | ns |
Total alcohols | 1312.99 | 1328.95 | 1246.23 | 26.32 | ns | ||
Pentane | 43 | 500 | 8.98 a,b | 7.65 b | 10.36 a | 0.45 | * |
3-methylpentane | 56 | 542 | 1.24 | 1.29 | 1.34 | 0.066 | ns |
Hexane | 57 | 600 | 134.71 | 117.53 | 115.89 | 4.50 | ns |
2-methylhexane | 85 | 620 | 0.76 c | 1.22 b | 1.72 a | 0.083 | *** |
3-methylhexane | 71 | 633 | 0.71 | 0.89 | 0.86 | 0.045 | ns |
Heptane | 71 | 700 | 23.76 b | 33.41 a | 36.33 a | 1.04 | *** |
3-ethylpentane | 71 | 759 | 422.57 a | 254.19 b | 232.08 b | 32.68 | * |
2,3,3-trimethylpentane | 70 | 767 | 395.27 b | 437.89 a | 454.87 a | 6.37 | *** |
2,3-dimethylhexane | 70 | 775 | 43.98 b | 101.96 a | 108.49 a | 6.04 | *** |
(E)-3,4-dimethylhex-2-ene | 83 | 779 | 35.79 c | 41.96 b | 46.82 a | 0.96 | *** |
2-methylheptane | 57 | 782 | 4.43 | 3.51 | 4.15 | 0.22 | ns |
Octane | 85 | 800 | 40.47 | 39.49 | 39.90 | 2.08 | ns |
2,3-dimethylheptane | 84 | 906 | 44.24 | 46.68 | 49.30 | 0.97 | ns |
3,4-dimethylheptane | 70 | 909 | 14.54 | 15.37 | 15.41 | 0.50 | ns |
2,2-dimethylpropane | 57 | 927 | 247.01 | 240.39 | 204.98 | 11.90 | ns |
2,6,6-trimethylbicyclo[3.1.1]hept-2-ene | 93 | 1000 | 21.85 a | 15.83 b | 22.74 a | 0.96 | ** |
Decane | 57 | 1000 | 758.56 | 769.19 | 658.41 | 47.48 | ns |
Tridecane | 71 | 1300 | 153.55 b | 177.51 a,b | 193.22 a | 6.41 | * |
Tetradecane | 57 | 1400 | 17.09 a | 14.44 a | 6.48 b | 0.89 | *** |
Pentadecane | 71 | 1500 | 2.63 | 2.36 | 2.49 | 0.13 | ns |
Lineal hydrocarbons | 1139.79 | 1161.59 | 1063.09 | 49.89 | ns | ||
Branched hydrocarbons | 1232.39 | 1161.18 | 1142.76 | 29.37 | ns | ||
Total hydrocarbons | 2372.14 | 2322.77 | 2205.84 | 66.73 | ns |
Control: 100% NaCl; Salt mixture I: 30% NaCl and 70% KCl; Salt mixture II: 30% NaCl, 50% KCl, 15% CaCl2 and 5% MgCl2; Volatile results are expressed as area units per gram of sample (AU × 104/g of sample). Sig.: significance; ns: not significant; * p < 0.05; ** p < 0.01; *** p < 0.001; a–c Mean values in the same row (corresponding to the same parameter) followed by a different letter differ significantly (p < 0.05; Duncan’s test). m/z: Quantifier ion.