Table 3.
1H NMR chemical shift data of 1 recorded in D2O at 310 K.
| Residue | H1 | H2 | H3 | H4 | H5 | H6a | H6b | H7a | H7b |
| →6)-α-GlcNI-(1→P | 5.77–5.73 | 3.50–3.45 | 3.96–3.91 | 3.65–3.60 | 4.15–4.10 | 3.83–3.78 | 4.31–4.27 | ||
| →6)-β-GlcNII4P-(1→ | 4.84 [d, 8.5 Hz] | 3.17–3.12 | 3.92–3.87 | 3.88–3.83 | 3.79–3.73 | 3.52–3.48 | 3.76-3.71 | ||
| →3)-α-HepI2P4P-(1→ | 5.39–5.36 | 4.54–4.51 | 4.22–4.17 | 4.54–4.48 | 4.30–4.26 | 4.14–4.09 | 3.83–3.79 | 3.99–3.94 | |
| →3)-α-HepII6P-(1→ | 5.15–5.12 | 4.39–4.36 | 4.21–4.18 | 4.13–4.09 | 4.05–4.00 | 4.56–4.50 | 3.77–3.71 | 3.82–3.77 | |
| →3,4)-α-GalN-(1→ | 5.60–5.57 | 3.88–3.83 | 4.43–4.39 | 4.46–4.44 | 4.24–4.21 | 3.84–3.80 | 3.93–3.88 | ||
| →2)-β-GlcI-(1→ | 4.75 [d, 7.9 Hz] | 3.38–3.34 | 3.77–3.73 | 3.40–3.36 | 3.50–3.45 | 3.73–3.69 | 3.97–3.93 | ||
| →6)-α-GlcII-(1→ | 5.03 [d, 7.9 Hz] | 3.55–3.50 | 3.76–3.72 | 3.68–3.63 | 4.22–4.18 | 3.81–3.78 | 3.95–3.92 | ||
| β-GlcNIII-(1→ | 4.94 [d, 8.4 Hz] | 3.29–3.22 | 3.74–3.68 | 3.61–3.55 | 3.58–3.53 | 3.95–3.85 | 3.95–3.85 | ||
| α-l-Rha-(1→ | 4.80–4.77 | 4.03–4.00 | 3.81–3.79 | 3.46–3.42 | 3.77–3.72 | 1.31 [d, 6.1 Hz] | |||
| Residue | H3eq | H3ax | H4 | H5 | H6 | H7 | H8a | H8b | |
| →4,5)-α-KdoI-(2→ | 2.30–2.23 | 2.04 [dd, 12.3, 12.0 Hz] | 4.17–4.12 | 4.31–4.27 | 3.74–3.71 | 3.89–3.85 | 3.63–3.58 | 3.93–3.88 | |
| α-KdoII-(2→ | 2.11 [dd, 12.9, 4.3 Hz] | 1.85 [dd, 12.9, 12.6 Hz] | 4.18–4.13 | 4.09–4.07 | 3.68–3.65 | 4.04–3.99 | 3.71–3.66 | 3.99–3.94 |