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(a) Ktrans/cis values for 7.41 and 7.42 in various solvents. (b) Computed Boltzmann-averaged dipole moments of trans and cis conformers for compounds 7.34 and 7.35. (c) Solvent influence on trans/cis ratios of peptide 7.7 and its effect of enantioselectivity. Ratios were determined by NMR analysis in DMSO-d6 and a 9:1 mixture of CDCl3:CD3OD. Reproduced in part from with permission from ref. 327. Copyright 2015. Royal Society of Chemistry.
