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. Author manuscript; available in PMC: 2021 Oct 28.
Published in final edited form as: Chem Rev. 2020 Sep 24;120(20):11479–11615. doi: 10.1021/acs.chemrev.0c00523

Figure 207.

Figure 207.

Application of peptide-based P,S-ligands 11.8 in the Pd-catalyzed allylation of malonate 11.5 with allylic acetate 11.6. Modular peptide synthesis enabled the assessment of many distinct stereochemical arrays.466