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(a) Design strategy for the encapsulation of achiral catalysts in homochiral, peptide-based Ti-phosphonate assemblies in aqueous environments. (b) Asymmetric hydrogenation of acetophenone 11.31 catalyzed by achiral Ru complexes encapsulated by 11.29 and 11.30.477 (c) Asymmetric epoxidation/ring-opening of styrenes 11.33 catalyzed an achiral Mn-salen complex encapsulated by 11.29.476
