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. Author manuscript; available in PMC: 2021 Oct 28.
Published in final edited form as: Chem Rev. 2020 Sep 24;120(20):11479–11615. doi: 10.1021/acs.chemrev.0c00523

Figure 224.

Figure 224.

(a) Atroposelective cyclodehydration of trifluoroacetamides 11.82 to benzimidazoles 11.83 catalyzed by pThr-containing peptides. (b) Catalyst-controlled diastereoselective cyclodehydration of enantioenriched 11.86.498