Skip to main content
. Author manuscript; available in PMC: 2021 Oct 28.
Published in final edited form as: Chem Rev. 2020 Sep 24;120(20):11479–11615. doi: 10.1021/acs.chemrev.0c00523

Figure 23.

Figure 23.

(a) Asp-containing peptide catalysts for BV oxidation and epoxidation. (b) Dual substrate trans-2.69, containing both a 3-amidocyclohexanone motif for BV oxidation and an allylic alcohol for epoxidation. While achiral catalysts provide limited selectivity, catalysts 2.68c and 2.34b facilitated their matched reactivities. (c) Model for selective BV oxidation with ent-2.68c. (d) Model for selective epoxidation with 2.34b.78