Table 4. Rate Coefficients for the H₂S + Cl Reaction at Various Temperatures (Pressure = 1 atm)^a,b.

T (K)	VRC-VTSTin	VTST-VTSTin	PST-VTSTin
200	1.01 × 10–10	1.02 × 10–10	1.31 × 10–10
225	9.49 × 10–11	9.53 × 10–11	1.22 × 10–10
250	8.94 × 10–11	9.03 × 10–11	1.14 × 10–10
275	8.51 × 10–11	8.64 × 10–11	1.08 × 10–10
300	8.16 × 10–11	8.33 × 10–11	1.03 × 10–10
325	7.89 × 10–11	8.07 × 10–11	9.84 × 10–11
350	7.63 × 10–11	7.87 × 10–11	9.50 × 10–11
375	7.44 × 10–11	7.69 × 10–11	9.21 × 10–11
400	7.26 × 10–11	7.56 × 10–11	8.98 × 10–11
425	7.13 × 10–11	7.45 × 10–11	8.78 × 10–11
450	6.99 × 10–11	7.36 × 10–11	8.62 × 10–11
475	6.89 × 10–11	7.29 × 10–11	8.49 × 10–11
500	6.80 × 10–11	7.24 × 10–11	8.38 × 10–11
600	6.56 × 10–11	7.17 × 10–11	8.16 × 10–11
700	6.45 × 10–11	7.24 × 10–11	8.16 × 10–11
800	6.41 × 10–11	7.41 × 10–11	8.31 × 10–11
900	6.44 × 10–11	7.65 × 10–11	8.57 × 10–11

^aThe various prefixes stand for the theoretical methods used to handle the barrierless entrance channel, while the VTSTin suffix means that the inner TS is handled with VTST in curvilinear internal coordinates. The barrierless exit channel is always treated with PST.

^bValues in cm³ molecule^–1 s^–1.