Table 2. AE_exp and Adiabatic AE_th for the Main Fragment Ions from ClCH₂I at 298 K.

ClCH2I
ions (m/z)	AEexp (eV)	AEexpa (eV)	AEth (eV)
[ClCH2I]•+ (176)	9.71 ± 0.01	9.752 ± 0.012	9.70
CH2Cl+ (49) + I	10.79 ± 0.01	10.878 ± 0.010	10.87
CH2I+ (141) + Cl	11.66 ± 0.03	11.656 ± 0.030	11.46
I+ (127) + CH2Cl	13.15 ± 0.19		12.83
ICl+ (162) + CH2	15.01 ± 0.02		14.01
CI+ (139)	15.63 ± 0.01
CCl+ (47)	14.88 ± 0.01

^aReference (44).