Table 1. Thermodynamic Parameters Evaluated from Micro-DSC Thermograms Obtained from the Modeling of a Simplified Model Membranea.
expected |
experimental |
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Δ H° (kJ·mol–1) | Texpected (°C) | ΔH° (kJ·mol–1) | Tmax (°C) | T̅ (°C) | ACI (°C) | |
3:2 DMPC:DPPS | 30 | 36.4 | 30 ± 2 | 32.6 ± 0.1 | 34.5 ± 0.1 | 2.8 ± 0.1 |
5.7:3.8:0.5 DMPC:DPPS:DOPC | 29 | – | 26 ± 2 | 32.6 ± 0.6 | 30.1 ± 0.1 | 5.3 ± 0.1 |
The parameters were compared with the arithmetical values calculated from single-component systems. The last cycle heating curves were used to obtain the main transition enthalpy (ΔH°), the peak maximum temperature (Tmax), the transition average temperature (T̅), and the average cooperativity index (ACI).