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. 2021 Feb 9;21(4):1591–1598. doi: 10.1021/acs.nanolett.0c03756

Table 2. T1 Relaxation Time of Protons from −CH2–CH2– Units in the PEG Main Chain and −CH3 End Groups for PEG2k and OVA-PEG Samples with Various Molecular Weights and Surface Grafting Densitiesa.

entry T1 (−CH2–CH2−) [s] SD (×10–3) T1 (−CH3) [s] SD (×10–2) φ (−CH2CH2–/–CH3)
PEG2k 1.30 1.62 2.61 1.54 62
OVA-PEG2k0.2 1.41 1.24 3.91 1.31 91
OVA-PEG2k0.5 1.37 1.33 3.03 2.52 78
OVA-PEG2k2.5 1.33 1.79 2.82 1.82 43
OVA-PEG3.4k0.2 1.42 1.61 3.61 2.44 76
OVA-PEG3.4k0.8 1.34 1.17 3.42 1.29 65
OVA-PEG5k0.2 1.46 2.35 3.79 1.93 196
a

φ represents the ratio of integrals of signals corresponding to −CH2–CH2– and −CH3 end groups determined by 1H NMR spectroscopy.