Table 2. T1 Relaxation Time of Protons from −CH2–CH2– Units in the PEG Main Chain and −CH3 End Groups for PEG2k and OVA-PEG Samples with Various Molecular Weights and Surface Grafting Densitiesa.
| entry | T1 (−CH2–CH2−) [s] | SD (×10–3) | T1 (−CH3) [s] | SD (×10–2) | φ (−CH2CH2–/–CH3) |
|---|---|---|---|---|---|
| PEG2k | 1.30 | 1.62 | 2.61 | 1.54 | 62 |
| OVA-PEG2k0.2 | 1.41 | 1.24 | 3.91 | 1.31 | 91 |
| OVA-PEG2k0.5 | 1.37 | 1.33 | 3.03 | 2.52 | 78 |
| OVA-PEG2k2.5 | 1.33 | 1.79 | 2.82 | 1.82 | 43 |
| OVA-PEG3.4k0.2 | 1.42 | 1.61 | 3.61 | 2.44 | 76 |
| OVA-PEG3.4k0.8 | 1.34 | 1.17 | 3.42 | 1.29 | 65 |
| OVA-PEG5k0.2 | 1.46 | 2.35 | 3.79 | 1.93 | 196 |
φ represents the ratio of integrals of signals corresponding to −CH2–CH2– and −CH3 end groups determined by 1H NMR spectroscopy.