. 2021 Mar 12;77(Pt 4):383–389. doi: 10.1107/S2056989021002425

Table 1. A comparison of structural parameters (Å, °) in Cp′₃U(BH₄) and other Cp′₃UX {X = Cl⁻, I⁻, [Si(SiMe₃)₃]⁻} complexes.

cent = C₅H₄SiMe₃ centroid.

	Cp′₃U(BH₄)	Cp′₃UCl^a (Windorff et al., 2017 ▸)	Cp′₃UI (Windorff et al., 2017 ▸)	Cp′₃U(η ¹-CH=CH₂) (Schock et al., 1988 ▸)	Cp′₃U[Si(SiMe₃)₃] (Réant et al., 2020 ▸)
U—(cent)	2.458, 2.490, 2.500	2.473	2.475, 2.478, 2.480	2.481, 2.483, 2.489	2.472, 2.478, 2.485
(cent)—U—X	104.13, 104.14, 104.83	100.00	97.9, 101.2, 101.6	95.1 100.0 100.2	96.04, 96.30, 97.65
(cent)—U—(cent)	113.28, 114.26, 114.26	117.00	116.1, 116.4, 118.3	116.4, 117.2, 120.0	118.28, 118.88, 119.08

Note: (a) The asymmetric unit contains one Cp′ ring, one-third of a chloride atom, and one-third of a uranium atom.

Table 1. A comparison of structural parameters (Å, °) in Cp′3U(BH4) and other Cp′3UX {X = Cl−, I−, [Si(SiMe3)3]−} complexes.