Table 3. Experimental details.
| Crystal data | |
| Chemical formula | [Co(NCS)2(C6H8N2)2] |
| M r | 391.38 |
| Crystal system, space group | Monoclinic, P21/n |
| Temperature (K) | 200 |
| a, b, c (Å) | 8.2442 (4), 11.9186 (4), 8.9204 (4) |
| β (°) | 100.807 (4) |
| V (Å3) | 860.97 (6) |
| Z | 2 |
| Radiation type | Mo Kα |
| μ (mm−1) | 1.25 |
| Crystal size (mm) | 0.20 × 0.15 × 0.12 |
| Data collection | |
| Diffractometer | STOE IPDS2 |
| Absorption correction | Numerical (X-AREA; Stoe & Cie, 2002 ▸) |
| T min, T max | 0.709, 0.886 |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 13295, 1871, 1702 |
| R int | 0.029 |
| (sin θ/λ)max (Å−1) | 0.638 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.029, 0.071, 1.15 |
| No. of reflections | 1871 |
| No. of parameters | 106 |
| H-atom treatment | H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) | 0.30, −0.23 |